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. Author manuscript; available in PMC: 2006 May 2.
Published in final edited form as: Rapid Commun Mass Spectrom. 2003;17(7):637–645. doi: 10.1002/rcm.960

Table 3.

Results of the LC/APCI-MS/MS analysis of aldehydes (nM) produced by lipid peroxidation of membranes in breath condensate of healthy nonsmoking subjects and asymptomatic smokers, and determined as DNPH derivatives

Healthy (n = 12)
Smokers (n = 13)
Median Range Median Range
MDA 11.2 1.07–23.4 34.7* 16.4–56.9
Acrolein 2.33 1.39–3.95 6.78* 6.26–7.45
4-HHE 0.94 0.85–12.6 4.72 2.56–33.9
4-HNE 0.74 0.25–9.04 3.77 0.74–5.75
n-hexanal 41.9 8.34–87.3 68.6* 38.4–75.2
n-heptanal 29.9 7.93–46.8 30.8 14.9–39.5
n-nonanal 17.8 6.68–27.7 12.9 4.72–24.7
*

p < 0.05, vs. nonsmoking subjects.