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. 2006 Jun;188(12):4424–4430. doi: 10.1128/JB.01849-05

FIG. 4.

FIG. 4.

Proposed mechanisms for the BphK-catalyzed dehalogenation of 3-Cl HOPDA. The upper mechanism proceeds through addition/elimination steps. The lower mechanism is similar to the SN2 reaction that was ruled out for the TCHQ dehalogenase reaction. Enz, enzyme.