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. 2003 Mar 4;100(5):2316–2321. doi: 10.1073/pnas.0337708100

Figure 3.

Figure 3

HPLC analysis of culture extracts of the cloQ and cloI mutants. (A) Clorobiocin standard, wild type, cloQ mutant, and cloQ mutant fed with ring A. Detection was at 340 nm. The identity of clorobiocin ([M − H] = 695) was confirmed by LC-ESI-CID. Mass spectroscopic fragments are indicated. (B) Clorobiocin standard, wild type, and cloI mutant. Detection was at 340 nm. (C) Ring A standard, wild type, and cloI mutant. Detection was at 254 nm. The identity of ring A ([M − H] = 205) was confirmed by LC-ESI-CID. Mass spectroscopic fragments are indicated.