Table 3.

Hydroamination of Aryl-Substituted Aminoallenes (5 Mol % of Catalyst in C₆D₆, 75°C)

					isolated yielda
entry	substrate	major product	cat.	t / h	imine	allyamine
1			3	22	(95)	(5)
2			13	1	84	---
3			3	9	(90)	(10)
4			13	5	79	---
5			3	4	(92)	(8)
6			13	1.5	95	---
7			13	10	93	---
8			13	2	88	---
9			13b	3	(93)	(7)
10		---	13b	24	---	---

^a Yields in parentheses refer to ratio of imine/allylamine by NMR after complete and selective conversion of the starting material (versus internal standard)

^b 10 mol %.