. Author manuscript; available in PMC: 2006 Sep 25.

Published in final edited form as: J Am Chem Soc. 2003 Oct 1;125(39):11956–11963. doi: 10.1021/ja0361547

Table 7.

Synthesis of Allylamines Using Zirconium Catalysts 21

entry	product	T / °C	yield (%)^a	Z/E	regioselectivity
1		75	62^b	> 20 / 1	4 / 1
1	24	75	62^b	> 20 / 1	4 / 1
2		75	68	> 20 / 1	7 / 1
2	25	75	68	> 20 / 1	7 / 1
3		135^c	88	1.8 / 1	11 / 1
3	26	135^c	88	1.8 / 1	11 / 1

Isolated as the trifluoroacetamide derivative.

By ¹H NMR.

10 mol % 21.