. 2006 May 25;386(3):666–674. doi: 10.1007/s00216-006-0495-1

Table 1.

Characteristic fragmentation of selected sulfated products

Group	No.	Chemical name	Abundance of characteristic ions in MS/MS (%)
Group	No.	Chemical name	m/z [M-80]^-	m/z 80	m/z 96	m/z 97
a	1	4-nitrocatechol sulfate	100^a	–	–	–
	2	L-ascorbic acid 2-sulfate	31^a	–	–	–
	3	Indoxyl sulfate	24^a	52	–	–
	4	4-nitrophenyl sulfate	100^a	–	–	–
	5	β-estradiol 3-sulfate	100^a	–	–	–
	6	5-Br-4-Cl-3-indolyl sulfate	47^a	59	–	–
	7	4-methylumbelliferyl sulfate	100^a	–	–	–
b	8	2-aminoethyl hydrogen sulfate	–	100	18	67^a
	9	Poly (vinyl sulfate)	–	–	–	97^a
	10	D-glucose 6-sulfate	–	–	–	100^a
	11	Chondroitin disaccharide Δdi-6S	–	–	–	31^a
	12	N-acetylglucosamine 6-sulfate	–	–	–	93^a
c	13	2-naphthalenemethanol, α-methyl- sulfate	–	6.7	7.3^a	100
	14	Benzyl sulfate	–	16	100^a	–
	15	(R)-1-phenyl-2-propen-1-sulfate	–	26	100^a	12
	16	4-Cl-2-methylbenzyl sulfate	–	–	100^a	95
	17	3-ethoxybenzyl sulfate	–	100	13^a	6.4
	18	2-ethoxybenzyl sulfate	–	100	17^a	8.5
	19	4-ethoxybenzyl sulfate	–	100	20^a	8.7
	20	crotyl sulfate	–	55	91^a	50
	21	furfuryl sulfate	–	–	53^a	39
d	22	N-methyl-hydroxylamine-O-sulfonic acid	–	100	73^a	9.2
	23	N-isopropyl- hydroxylamine-O-sulfonic acid	–	68	100^a	5.1
	24	N-cyclohexyl-hydroxylamine-O-Sulfonic acid	–	27	100^a	11
	25	N,N-diethyl-hydroxylamine-O-sulfonic acid	–	92	100^a	19
	26	N-benzoyl-N-phenyl-hydroxylamine-O-sulfonic acid	–	–	100^a	–
e	27	N-cyclohexylsulfamic acid	–	100^a	–	–
	28	4-methylphenyl-Sulfamic acid	–	100^a	–	–
	29	3-hydroxypropyl-sulfamic acid	–	100^a	–	–
	30	D-glucosamine 2-sulfate	–	100^a	–	–
	31	butyl-sulfamic acid	–	100^a	–	–
	32	(R)(+)-α-phenethylsulfamic acid	–	100^a	–	–

*A threshold of 5.0% is used for the relative abundance of characteristic ions. The long dash (–) means that the characteristic ion can not be detected or the relative abundance is below 5.0%

^aRepresents the specific characteristic ion of each group that can help to identify the sulfation site