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. 2006 Oct 13;399(Pt 3):503–511. doi: 10.1042/BJ20060567

Table 3. Affinity of AkCBM42 to oligosaccharide estimated by ITC.

Protein Ligand Ka(×103 M−1) ΔG (kcal·mol−1) ΔH (kcal·mol−1) S (kcal·mol−1) na Mtotb (mM) c
E221A mA1 1.6 (±0.05)c −4.4 −5.0 (±0.05) −0.6 2.0 0.6 1.9
E221A A3 2.7 (±0.2) −4.7 −3.6 (±0.09) 1.1 2.0 0.4 2.1
E221A mX1 NDd ND ND ND ND
E221A X3 ND ND ND ND ND
E221A glucose ND ND ND ND ND
E221A/D435A mA1 8.3 (±0.3) −5.4 −1.0 (±0.01) 4.4 1.0 0.2 1.7
E221A/D488A mA1 1.3 (±0.02) −4.2 −3.0 (±0.02) 1.2 1.0 0.3 0.4
E221A/D435A/D488A mA1 ND ND ND ND ND
E221A/D435A/D488A A3 ND ND ND ND ND

aNumber of binding sites on the protein. The values were fixed for curve fitting.

bThe total protein concentration in the cell.

cValues in parentheses are S.D. from the fit.

dND, not detected.