. 2006 Oct 10;103(42):15309–15314. doi: 10.1073/pnas.0602675103

Table 1.

ICAR ATRP of styrene (St), methyl methacrylate (MMA), and n-butyl acrylate (BA)

Entry	Temp, °C	Monomer/initiator/Cu	[Cu], ppm	Ligand/ratio to Cu	AIBN/Initiator	Time, min	Conv., %	M_n		M_w/M_n
Entry	Temp, °C	Monomer/initiator/Cu	[Cu], ppm	Ligand/ratio to Cu	AIBN/Initiator	Time, min	Conv., %	Theoretical	GPC	M_w/M_n
1	60	200 St/1/0.01	50	Me₆TREN/1	0.1	2,760	44	8,700	7,900	1.12
2	60	200 St/1/0.01	50	TPMA/1	0.1	2,880	39	7,800	6,800	1.09
3	60	200 St/1/0.01	50	PMDETA/1	0.1	2,880	29	5,600	4,500	1.62
4	60	200 St/1/0.01	50	dNbpy/2	0.1	2,940	36	7,200	5,600	1.68
5	70	200 St/1/0.01	50	Me₆TREN/1	0.1	2,400	47	9,500	7,600	1.11
6	70	200 St/1/0.01	50	Me₆TREN/1	0.2	2,500	60	11,900	10,000	1.15
7	70	200 St/1/0.01	50	Me₆TREN/1	0.4	1,140	66	13,200	10,100	1.22
8	110	200 St/1/0.01	50	Me₆TREN/10	—	1,775	65	12,900	11,000	1.25
9	110	200 St/1/0.01	50	TPMA/10	—	1,930	49	9,800	9,600	1.13
10	110	200 St/1/0.002	10	TPMA/50	—	1,720	42	8,400	7,600	1.38
11	110	200 St/1/0.0002	1	TPMA/500	—	1,700	55	11,000	8,400	1.72
12	60	200 MMA/1/0.01	50	TPMA/1	0.1	1,120	50	10,100	11,100	1.23
13	65	200 BA/1.25/0.01	50	TPMA/1	0.01	1,910	35	7,100	8,900	1.46

Boldface numbers emphasize the variable of interest in a series of experiments. Ratios are molar. AIBN, azobisisobutyronitrile; GPC, gel-permeation chromatography; EtBrPA, ethyl α-bromophenylacetate. [St]₀/[EtBrIB]₀ = 200; [St]₀ = 5.82 M; 50% anisole by volume; [BA]₀/[EtBrIB]₀ = 160; [BA]₀ = 5.88 M; 20% anisole by volume; [MMA]₀/[EtBrPA]₀ = 200; [MMA]₀ = 6.23 M; 50% anisole by volume.