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. 2006 Mar 23;2006:75612. doi: 10.1155/BCA/2006/75612

Table 10.

Electronic spectral data of few Ln(III) complexes of BIA.

Complex Assignments λ max of Ln+3 λ max of complex β Other parameters
ion(cm−1) (cm−1)

(1) [Pr3(BIA)2(NO3)7(H2O)4] 3H2O 3H4- - -3P2 22 512 22 502 0.999 55
- - -3P0 20 716 20 678 0.998 16 δ = 0.105 11
- - -1D2 16 854 16 840 0.999 16 b1/2 = 0.022 91

η = 0.032 42
0.998 95

(2) [Nd3(BIA)2(NO3)7(H2O)4] 3H2O 4I9/2- - -2G9/2 19 747 19 565 0.990 78
- - -4G5/2 17 253 17 182 0.995 88 δ = 0.707 97
- - -4F9/2 14 594 14 450 0.990 13 b1/2 = 0.0592
- - -4F5/2 12 853 12 790 0.995 09 η = 0.084 14

0.992 97