Table 10.
Complex | Assignments | λ max of Ln+3 | λ max of complex | β | Other parameters |
ion(cm−1) | (cm−1) | ||||
| |||||
---|---|---|---|---|---|
(1) [Pr3(BIA)2(NO3)7(H2O)4] 3H2O | 3H4- - -3P2 | 22 512 | 22 502 | 0.999 55 | |
- - -3P0 | 20 716 | 20 678 | 0.998 16 | δ = 0.105 11 | |
- - -1D2 | 16 854 | 16 840 | 0.999 16 | b1/2 = 0.022 91 | |
|
η = 0.032 42 | ||||
0.998 95 | |||||
| |||||
(2) [Nd3(BIA)2(NO3)7(H2O)4] 3H2O | 4I9/2- - -2G9/2 | 19 747 | 19 565 | 0.990 78 | |
- - -4G5/2 | 17 253 | 17 182 | 0.995 88 | δ = 0.707 97 | |
- - -4F9/2 | 14 594 | 14 450 | 0.990 13 | b1/2 = 0.0592 | |
- - -4F5/2 | 12 853 | 12 790 | 0.995 09 | η = 0.084 14 | |
|
|||||
0.992 97 |