Table 7.
Compound | Found (Calcd) (%) | Magnetic a moment | Molar conductivity b | |||
M | C | H | N | |||
| ||||||
---|---|---|---|---|---|---|
(1) BIA | — | 16.29 | 2.15 | 11.62 | — | — |
(16.25) | (2.10) | (11.59) | ||||
(2) [La3(BIA)2(NO3)7(H2O)4] · 3H2O | 31.65 | 16.24 | 2.11 | 11.58 | dia | 7.6 |
(31.70) | (16.18) | (2.09) | (1.53) | |||
(3) [Pr3(BIA)2(NO3)7(H2O)4] · 3H2O | 32.14 | 16.16 | 2.16 | 11.40 | 3.55 | 7.2 |
(32.10) | (16.06) | (2.08) | (11.45) | |||
(4) [Nd3(BIA)2(NO3)7(H2O)4] · 3H2O | 32.74 | 15.91 | 2.13 | 11.35 | 3.61 | 8.3 |
(32.61) | (15.84) | (2.05) | (11.29) | |||
(5) [Sm3(BIA)2(NO3)7(H2O)4] · 3H2O | 33.42 | 15.85 | 2.01 | 11.19 | 1.64 | 6.9 |
(33.53) | (15.79) | (2.04) | (11.25) | |||
(6) [Eu3(BIA)2(NO3)7(H2O)4] · 3H2O | 34.69 | 15.68 | 2.07 | 11.17 | 3.40 | 7.7 |
(34.66) | (15.60) | (2.02) | (11.12) | |||
(7) [Gd3(BIA)2(NO3)7(H2O)4] · 3H2O | 34.46 | 15.66 | 2.06 | 11.13 | 7.79 | 8.6 |
(34.54) | (15.55) | (2.01) | (11.08) | |||
(8) [Tb3(BIA)2(NO3)7(H2O)4] · 3H2O | 34.67 | 15.52 | 2.01 | 11.12 | 9.82 | 4.4 |
(34.77) | (15.43) | (2.0) | (11.0) | |||
(9) [Dy3(BIA)2(NO3)7(H2O)4] · 3H2O | 35.21 | 18.00 | 2.25 | 13.17 | 10.30 | 9.6 |
(35.28) | (18.32) | (2.37) | (13.06) | |||
(10) [Y3(BIA)2(NO3)7(H2O)4] · 3H2O | 23.01 | 47.16 | 3.49 | 18.70 | dia | 8.0 |
(22.97) | (47.06) | (3.50) | (18.78) |
aBM. bOhm−1 cm2 mol−1.