Table 2.
Sequences of lipopeptide adducts resolved by HPLC (Fig. 2)
Peak | Sequence | Mr | Involucrin sequence |
---|---|---|---|
1 | ELEEEK | 775.8 | Q122 LEEEK |
2 | DQELNK | 745.8 | DQQ118LNK |
3 | AENPEQELK | 1,057.1 | AENPEQQ107LK |
4 | LLDQELDQELVK | 1,442.7 | LLDQQ133LDQELVK |
5 | QEAQLELPEQEVGQPK | 1,833.9 | QEAQLELPEQQ496VGQPK |
Boldface letters indicate the modified glutamines participating in the ester formation.