Table 1.

Complete ¹H and ¹³C chemical shift assignments of PS A2 residues

	Residue		1	2	3	4	5	6	7	NAc* (C = O)
a	→3)-α-d-AATp-(1→	1H	5.26	3.99	4.32	4.46	4.59	1.10
		13C	98.41	50.92	74.25	55.27	66.56	17.08		175.51
b	α-l-Fucp-(1→	1H	4.97	3.69	3.59	3.65	4.14	1.17
		13C	100.18	69.06	71.02	72.97	67.80	16.87
c	→2)-α-d-Hepp-[6→Bu]-(1→	1H	4.84	3.85	3.75	3.92	3.41	4.08	3.77
		13C	97.43	76.21	75.17	67.69	76.33	70.03	64.03
d	→3)-β-d-ManNAcp-(1→	1H	4.79	4.60	3.95	3.56	3.44	3.84, 3.94
		13C	100.48	50.85	78.24	66.65	77.77	61.97		175.67
e	→4)-β-d-ADGp-[2→](1→	1H	4.70	3.48	4.01	3.43	3.54	1.29
		13C	103.81	76.83	56.60	82.84	73.11	18.14		175.68
	Bu-(3→	1H		2.56	4.23	1.26
		13C	175.42	45.99	66.34	23.02

Chemical shifts are reported in ppm. AAT, 2-amino-4-acetamido-2,4,6-trideoxygalactose; ManNAc, N-acetyl mannosamine; ADG, 3-acetamido-3,6-dideoxyglucose. 

^*The methyls in all three NAc groups have the same chemical shifts: δ_H 2.05 ppm and δ_C 23.41 ppm.