TABLE 2.

Thermodynamic parameters obtained from the reaction constants determined through kinetics and equilibrium data with different ΔC_p (in cal mol⁻¹ K⁻¹ per basepair)

Probe		Kinetics		Equilibrium
	ΔCp	ΔH (kJ mol−1)	ΔS (J mol−1 K−1)	ΔH (kJ mol−1)	ΔS (J mol−1 K−1)
P9	0	−262 ± 13	−723 ± 42	−199 ± 63	−516 ± 206
	−50	−267 ± 12	−734 ± 39	−203 ± 63	−532 ± 207
	−100	−271 ± 12	−754 ± 36	−208 ± 64	−547 ± 209
P10	0	−203 ± 17	−523 ± 53	−167 ± 14	−406 ± 44
	−50	−200 ± 17	−514 ± 54	−165 ± 13	−397 ± 44
	−100	−198 ± 17	−507 ± 55	−162 ± 14	−390 ± 44
P12	0	−150 ± 12	−346 ± 40	−108 ± 18	−207 ± 57
	−50	−144 ± 12	−327 ± 38	−102 ± 16	−188 ± 53
	−100	−139 ± 11	−308 ± 37	−97 ± 15	−169 ± 48
P14	0	−87 ± 23	−139 ± 75	−27 ± 6	60 ± 20
	−50	−80 ± 24	−117 ± 78	−20 ± 6	82 ± 18
		−100	−73 ± 25	− 95 ± 82	−13 ± 6	10 ± 19