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Orthogonal multivalent interactions on interfaces and between interfaces. (a) Vesicle surface saturated with Cu(II) and L. CuL2 is the only significant species. (b) Vesicle surface saturated with Ni(II) and L. L largely saturates the CD sites, but many vacant coordination sites on Ni(II) and L are available. (c) Two vesicles interacting via multiple coordination sites on Ni(II) and L.
