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. Author manuscript; available in PMC: 2008 Mar 15.
Published in final edited form as: Arch Biochem Biophys. 2006 Nov 22;459(2):233–240. doi: 10.1016/j.abb.2006.11.016

Scheme 2.

Scheme 2

PtlF-catalyzed conversion of 1-deoxy-11β-hydroxypentalenic acid (9) to 1-deoxy-11-oxopentalenic acid (10) and proposed oxidative conversion to pentalenolactone D (5).