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. 2006 Nov 6;103(46):17088–17093. doi: 10.1073/pnas.0603978103

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© 2006 by The National Academy of Sciences of the USA

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Scheme 2. — Generalized Chatt-type mechanism for the reduction of dinitrogen to ammonia catalyzed at a single metal accommodating oxidation states n to n + 3. For the case of MMo and Fe, n = +3 and +1, respectively.

Inline graphic — Generalized Chatt-type mechanism for the reduction of dinitrogen to ammonia catalyzed at a single metal accommodating oxidation states n to n + 3. For the case of MMo and Fe, n = +3 and +1, respectively.