Table 1.
Run n | t, °C | Time, h | Initial composition, wt % |
Diamond nucleation | Mechanism Gr → Dm transformation | α Gr → Dm transformation, % | Diamond morphology | Metastable graphite | ||
---|---|---|---|---|---|---|---|---|---|---|
KCl | K2CO3 | H2O | ||||||||
550/2 | 1,800 | 10 | 100 | — | — | — | — | 0 | — | — |
555/2 | 1,800 | 15 | 100 | — | — | — | — | 0 | — | — |
548/2 | 1,800 | 20 | 100 | — | — | + | FG | 2 | {111} | — |
557/2 | 1,600 | 20 | 100 | — | — | — | — | 0 | — | — |
1043B | 1,600 | 15 | 80 | 20 | — | + | FG, TGG | 100 | {111}, {100} | — |
1048B | 1,600 | 15 | 50 | 50 | — | + | FG, TGG | 100 | {111}, {100} | — |
1043A | 1,600 | 15 | 50 | 50 | — | + | FG, TGG | 100 | {111}, {100} | — |
1048A | 1,600 | 15 | 25 | 75 | — | + | FG, TGG | 100 | {111}, {100} | — |
559/2 | 1,600 | 15 | — | 100 | — | + | FG, TGG | 100 | {111}, {100} | — |
1036A | 1,550 | 15 | — | 100 | — | + | FG, TGG | 90 | {111}, {100} | — |
1036B | 1,550 | 15 | 24 | 76 | — | + | FG, TGG | 80 | {111}, {100} | — |
1053A | 1,500 | 15 | — | 100 | — | + | FG, TGG | 2 | {111}, {100} | — |
1053B | 1,500 | 15 | 50 | 50 | — | + | FG, TGG | 1 | {111}, {100} | — |
1035A | 1,400 | 15 | – | 100 | — | — | — | — | — | + |
1035B | 1,400 | 15 | 30 | 70 | — | — | — | — | — | + |
1060B | 1,600 | 15 | — | 81 | 19 | + | TGG | 6 | {111} | — |
1046B | 1,600 | 15 | — | 65 | 35 | + | TGG | 100 | {111} | — |
1045B | 1,600 | 15 | — | 37 | 63 | + | TGG | 100 | {111} | — |
1038B | 1,500 | 15 | — | 83 | 17 | + | TGG | <1 | {111} | + |
1054A | 1,500 | 15 | — | 65 | 35 | + | TGG | 4–5 | {111} | + |
1038A | 1,500 | 15 | — | 48 | 52 | + | TGG | 8 | {111} | + |
1062B | 1,500 | 15 | — | 10 | 90 | + | TGG | 70 | {111} | — |
1042A | 1,600 | 15 | 83 | — | 17 | + | TGG | 2 | {111} | + |
1060A | 1,600 | 15 | 68 | — | 32 | + | TGG | 4 | {111} | + |
1046A | 1,600 | 15 | 34 | — | 66 | + | TGG | 100 | {111} | — |
1042B | 1,600 | 15 | 31 | — | 69 | + | TGG | 100 | {111} | — |
745/2 | 1,600 | 15 | — | — | 100 | + | TGG | 95 | {111} | — |
1058A | 1,500 | 15 | 81 | — | 19 | — | — | 0 | — | + |
1054B | 1,500 | 15 | 65 | — | 35 | + | TGG | <1 | {111} | + |
1061A | 1,500 | 15 | 53 | — | 47 | + | TGG | 4 | {111} | + |
1062A | 1,500 | 15 | 9 | — | 91 | + | TGG | 70 | {111} | + |
1061B | 1,500 | 15 | — | — | 100 | + | TGG | 60 | {111} | — |
1085B | 1,500 | 15 | 40 | 36.5 | 23.5 | + | TGG | <1 | {111} | + |
1086A | 1,500 | 15 | 20.1 | 39.7 | 40.2 | + | TGG | 5 | {111} | + |
1086B | 1,500 | 15 | 39.1 | 20.1 | 40.8 | + | TGG | 2 | {111} | + |
α is the degree of graphite-to-diamond transformation. α = MDm/(MDm+ MGr)100, where MDm is the mass of obtained diamond and MGr is the mass of residual graphite. Dm, diamond, Gr, graphite.