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. 2007 Mar 22;104(22):9122–9127. doi: 10.1073/pnas.0608134104

Table 1.

Experimental results at 7.5 GPa

Run n t, °C Time, h Initial composition, wt %
Diamond nucleation Mechanism Gr → Dm transformation α Gr → Dm transformation, % Diamond morphology Metastable graphite
KCl K2CO3 H2O
550/2 1,800 10 100 0
555/2 1,800 15 100 0
548/2 1,800 20 100 + FG 2 {111}
557/2 1,600 20 100 0
1043B 1,600 15 80 20 + FG, TGG 100 {111}, {100}
1048B 1,600 15 50 50 + FG, TGG 100 {111}, {100}
1043A 1,600 15 50 50 + FG, TGG 100 {111}, {100}
1048A 1,600 15 25 75 + FG, TGG 100 {111}, {100}
559/2 1,600 15 100 + FG, TGG 100 {111}, {100}
1036A 1,550 15 100 + FG, TGG 90 {111}, {100}
1036B 1,550 15 24 76 + FG, TGG 80 {111}, {100}
1053A 1,500 15 100 + FG, TGG 2 {111}, {100}
1053B 1,500 15 50 50 + FG, TGG 1 {111}, {100}
1035A 1,400 15 100 +
1035B 1,400 15 30 70 +
1060B 1,600 15 81 19 + TGG 6 {111}
1046B 1,600 15 65 35 + TGG 100 {111}
1045B 1,600 15 37 63 + TGG 100 {111}
1038B 1,500 15 83 17 + TGG <1 {111} +
1054A 1,500 15 65 35 + TGG 4–5 {111} +
1038A 1,500 15 48 52 + TGG 8 {111} +
1062B 1,500 15 10 90 + TGG 70 {111}
1042A 1,600 15 83 17 + TGG 2 {111} +
1060A 1,600 15 68 32 + TGG 4 {111} +
1046A 1,600 15 34 66 + TGG 100 {111}
1042B 1,600 15 31 69 + TGG 100 {111}
745/2 1,600 15 100 + TGG 95 {111}
1058A 1,500 15 81 19 0 +
1054B 1,500 15 65 35 + TGG <1 {111} +
1061A 1,500 15 53 47 + TGG 4 {111} +
1062A 1,500 15 9 91 + TGG 70 {111} +
1061B 1,500 15 100 + TGG 60 {111}
1085B 1,500 15 40 36.5 23.5 + TGG <1 {111} +
1086A 1,500 15 20.1 39.7 40.2 + TGG 5 {111} +
1086B 1,500 15 39.1 20.1 40.8 + TGG 2 {111} +

α is the degree of graphite-to-diamond transformation. α = MDm/(MDm+ MGr)100, where MDm is the mass of obtained diamond and MGr is the mass of residual graphite. Dm, diamond, Gr, graphite.