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. 2007 Jun 20;104(36):14221–14226. doi: 10.1073/pnas.0701710104

Fig. 3.

Fig. 3.

Schematic illustrations of the mechanism for the slow component of the vibrational dephasing. (a) Pure solvent: density variations caused by diffusive first solvent shell structural fluctuations. (b) Mixed solvent: diffusive density and compositional fluctuations in the first solvent shell.