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. 1998 Mar 31;95(7):3483–3488. doi: 10.1073/pnas.95.7.3483

Table 2.

Modulation of the rate of zinc transfer from MT-2 to apo-SDH by GSH and GSSG

[GSH], mM [GSSG], mM [GSH]/[GSSG] Rate constant,* M−1·s−1
0 3 0 81
0.375 3 0.125 101
0.75 3 0.25 120
1.2 3 0.4 183
1.5 3 0.5 204
3.0 3 1.0 187
6.0 3 2.0 203
1.5 0 —  30
1.5 0.375 4.0 44
1.5 1.5 1.0 124
1.5 3.0 0.5 204
*

Rate constants were calculated as described in the legend of Table 1

The apparent slight activation noted here in comparison with the data in Table 1 is likely due to small amounts of GSSG formed in the 1.5 mM GSH solution.