Table 2.

NMR Data^a of Mycothiazole-4,19-diol (6) in DMSO-d₆

position	δC	δH mult, J (Hz)	gHMBCb
1	156.6
2	36.1	2.98 m
3	36.7	1.55 m
4	73.7
5	135.0	5.35 bd, 16	4,7
6	129.8	5.62 m	4
7	35.2	1.98 m	5, 6, 8
		1.85 m
8	77.3	3.57 m
9	45.3
10	177.7
11	112.8	7.07 bs	12, 13
12	154.0
13	29.2	3.45 d, 7.5	11, 12, 14, 15
14	127.6c	5.69 dtt, 10.7, 7.3, 1.5
15	127.9c	5.51 dtt, 10.6, 7.3, 1.7
16	31.3	2.87 dddt, 7.5, 6.0, 1.5, 2.0	14, 15, 17, 18
17	136.7	5.82 ddt, 16.8, 10.3, 6.2
18	115.1	5.06 ddt, 16.9, 2.0, 1.8	16
		4.98 ddt, 10.3, 2.0, 1.8
19	68.8	3.16 bt, 5	5
20	25.9d	1.32 s	8, 9, 10, 21
21	23.6d	1.29 s	8, 9, 10, 20
O-Me	51.1	3.48 s	1
NH		6.87 bt, 5.5
OH-4		4.27 d, 3.7	3, 4, 5, 19
OH-8		4.52 m
OH-19		4.81 bt, 6.3

^a500/125 MHz ¹H/¹³C.

^bδ_H to δ_C.

^{c, d}Interchangeable assignments.