Table 1. SORI-CAD MS/MS results of the [M – H]– ion of d(C∧pC).
Calculated mass | Measured mass | Deviation (p.p.m.) | |
---|---|---|---|
[M – H]– | 513.1135 | 513.1154 | 3.7 |
513.1125 | –1.9 | ||
513.1156 | 4.1 | ||
H2O loss | 495.1029 | 495.1039 | 2.0 |
495.1041 | 2.4 | ||
495.1030 | 0.2 | ||
Deoxyribose loss | 415.0767 | 415.0767 | 0.0 |
415.0769 | 0.5 | ||
415.0763 | –1.0 | ||
(Deoxyribose + HPO3 + H2O) loss | 317.0998 | 317.0999 | 0.3 |
317.1002 | 1.3 | ||
317.0995 | –0.9 | ||
Base loss | 293.0426 | 293.0427 | 0.3 |
293.0428 | 0.7 | ||
293.0423 | –1.0 | ||
[Base – H]– | 219.0630 | 219.0624 | –2.7 |
219.0626 | –1.8 | ||
219.0625 | –2.3 | ||
[Deoxyribose + HPO3 + H2O – H]– | 195.0059 | 195.0055 | –1.8 |
195.0056 | –1.3 | ||
195.0054 | –2.3 |
Data were obtained from three independent measurements.