Table 2. Proton NMR chemical shift data in p.p.m. for d(CpC) (SM) and d(C∧pC) (XL) at room temperature in D2O.
H1′ | H2′ | H2” | H3′ | H4′ | H5′ | H5” | H5 | H6 | |
---|---|---|---|---|---|---|---|---|---|
Cp, SM | 6.30 | 2.43 | 2.31 | 4.56 | 4.15 | 4.15 | 4.09 | 6.05 | 7.89 |
Cp, XL | 6.25 | 2.58 | 2.54 | 4.52 | 4.43 | 3.98 | 3.67 | NA | 8.53 |
pC, SM | 6.22 | 2.57 | 2.34 | 4.72 | 4.20 | 3.84 | 3.77 | 6.03 | 7.80 |
PC, XL | 6.03 | 2.76 | 2.39 | 4.42 | 3.98 | 4.21 | 3.74 | 6.24 | 8.38 |
Water signal at 4.80 p.p.m. was used as reference, Cp designates the 5′ nucleoside, and pC designates the 3′ nucleoside.