Table 2.
Monomer | Conversion at which the UV light was extinguished (%) | Dark Polymerization (% conversion after the UV light was extinguished) | Rp at the conversion where the light was extinguished (s−1) |
---|---|---|---|
Hexyl Acrylate | 35 ± 1 | 3 ± 1 | 0.007 ± 0.002 |
Tetrahydrofurfuryl Acrylate | 35 ± 1 | 7 ± 2 | 0.02 ± 0.03 |
Hexanediol Diacrylate | 10 ± 2 | 7 ± 2 | 0.05 ± 0.02 |
Hexanediol Diacrylate | 40 ± 3 | 15 ± 3 | 0.08 ± 0.02 |
Cyclic Carbonate Acrylate | 35 ± 5 | 35 ± 3 | 0.16 ± 0.02 |
Phenyl Carbamate Ethyl Acrylate | 36 ± 8 | 40 ± 3 | 0.38 ± 0.03 |
Ethyl Linear Carbonate Ethyl Acrylate | 34 ± 3 | 25 ±3 | 0.09 ± 0.02 |
Polymerization conditions: light intensity = 5 mW/cm2, initiator concentration = 0.1 wt% DMPA, room temperature.