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Thermodynamic parameters for WKMe3 and WtbutylNle at 298 K (19)
| Peptide | ΔH°, kcal/mol | ΔS°, cal/mol·K | ΔCp°, cal/mol·K |
|---|---|---|---|
| WK | −2.6 (0.1) | −6.2 (0.2) | −180 (30) |
| WKMe3L | −0.1 (0.1) | +4.5 (0.3) | −240 (40) |
| WtBuNle | +2.0 (0.4) | +12.9 (1.4) | −330 (50) |
Parameters were determined from the temperature dependence of the Gly chemical shift from 0°C to 80°C. Errors (in parentheses) are determined from the fit. The error for ΔCp° values is estimated at 15%.
