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Corrected gas-phase nucleotide ionization potentials associated with the highest occupied phosphate and base orbitals and values of ΔΔGHYD
| Ionization potentials ΔΔGHYD, eV
|
||
|---|---|---|
| 5′-dCMP− | 5′-dTMP− | |
| P1 | 5.0* (2.2) | 5.2* (2.0) |
| B1 | 5.8† (1.0) | 6.0† (0.7) |
ΔΔGHYD values, in eV, are in parentheses.
Vertical ionization potential.
Adiabatic ionization potential.
