The IT MS2 product-ion spectrum of the [M – H]− ion of 16:0-(19:0/16:0)-PIM2 at m/z 1413.9 (a), and its MS3 product-ion spectra of the ions at m/z 1157 (1413 → 1157) (b), at m/z 1115 (1413 → 1115) (c), at m/z 803 (1413 → 803) (d), and at m/z 1175 (1413 → 1175) (e); panel (f) illustrates the IT MS2 product-ion spectrum of the homologous ion at m/z 1441.9, arising from 18:0-(19:0/16:0)-PIM2.