Table 2.

Amine scope^a

Entry	RR'NH/Base	Product	R/R'	Yield of 3 (%)b
1	NsNHNa	3d	Ns/H	86
2	ThphNHNa	3e	Thph/H	94
3	BusNHNa	3f	Bus/H	50 (28)c
4	H2NCN/t-BuOK	3g	CN/H	85
5	PhNH2	3h	Ph/H	94
6	Me2NH	3i	Me/Me	97
7	(TMS)2NH	3j	H/H	89

^a Reaction conditions: sulfinamide 1a (1.0 equiv), NCS (1.2 equiv) and RR'NH/Base (2.0 equiv) in dry acetonitrile (0.1 M) at room temperature. ^b Yield after column chromatography. ^c Yield of 2a after column chromatography in brackets.