Table 1.
[Fe(OEP)(NO3)] | [Fe(TPP)(NO3)] | |
---|---|---|
formula | C36H44FeN5O3 | C44H28FeN5O3 |
FW, amu | 650.61 | 730.56 |
a, Å | 13.209(3) | 10.0271(3) |
b, Å | 13.774(3) | 16.1341(5) |
c, Å | 19.258(4) | 16.1341(5) |
β, deg | 105.50(3) | 90.330(2) |
γ, deg | 90 | 90.330(2) |
V, Å3 | 3376.2(12) | 3399.24(17) |
space group | P21/c | P21/n |
Z | 4 | 4 |
μ, mm−1 | 0.489 | 0.495 |
radiation | MoKα, λ̄ = 0.71073 Å | MoKα, λ̄ = 0.71073 Å |
temperature, K | 293 | 100(2) |
final R indices [I > 2σ (I)] | R1 = 0.0502, wR2 = 0.1140 | R1 = 0.0447, wR2 = 0.1167 |
final R indices (all data) | R1 = 0.0802, wR2 = 0.1311 | R1 = 0.0704, wR2 = 0.1405 |