. Author manuscript; available in PMC: 2008 Oct 10.

Published in final edited form as: Polyhedron. 2007 Oct 10;26(16):4664–4672. doi: 10.1016/j.poly.2007.03.048

Table 2.

Details of FeNO₃ Geometry for All [Fe(por)(NO₃)] Complexes. Coordination Geometries are Illustrated in Figure 4.

Complex	Fe–O1^a	Fe–O2^a	δ^a,^b	N5–O1^a	N5–O2^a	N5–O3^a	ref.
[Fe(OEP)(NO₃)]^c	1.996(2)	3.042(2)	1.076	1.301(3)	1.212(3)	1.199(3)	15
[Fe(OEP)(NO₃)]^d	2.016(3)	2.644(3)	0.628	1.206(5)	1.208(6)	1.198(4)	tw
[Fe(TPP)(NO₃)]^e	2.019(4)	2.323(8)	0.304	1.203(6)	1.176(6)	1.188(5)	16
[Fe(TPP)(NO₃)]^f	2.125(3)	2.268(3)	0.143	1.199(4)	1.300(3)	1.217(3)	tw
[Fe(TPP)(NO₃)]^g	2.117(4)	2.121(4)	0.004	1.334(4)	1.271(4)	1.217(3)	tw
[Fe(TpivP)(NO₃)]	2.123(3)	2.226(3)	0.103	1.271(4)	1.252(4)	1.214(3)	17

Value in Å.

Difference between Fe–O1 and Fe–O2.

Monoclinic form.

Triclinic form.

Room temperature structure.

100 K structure, major orientation.

100 K structure, minor orientation.