Abstract
Values for the thermodynamic quantities (ΔF, ΔH, ΔS) in reactions in which complexes of adenine nucleotides with magnesium ion (ATPMg--, ADPMg-, AMPMg) are formed have been obtained by a microcalorimetric technique by using an isothermic Calvet's apparatus.
Experimental values measured at ionic strength μ = 0.2 indicate that complex formation reactions are driven by the entropic factor and that stability of complexes increases with length of the phosphate chain.
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Selected References
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