Table 1.
Solvent | T, °C | λem, nm ±2 | <r>, ±0.003 | α1, ±0.05 | τ1, ns ±0.3 | α2, ±0.05 | τ2, ns ±0.2 | <τ>/ns | φ, ±0.007 |
---|---|---|---|---|---|---|---|---|---|
Cyclohexane | |||||||||
10 | 1 | 2.0* | 1.8 | 0.081 | |||||
15 | 1 | 1.9* | 1.7 | 0.076 | |||||
20 | 590 | 0 | 1 | 1.8 | 1.6 | 0.071 | |||
30 | 1 | 1.7* | 1.5 | 0.067 | |||||
DMPC | |||||||||
15 | 560 | 0.243 | 0.64 | 1.1 | 0.36 | 4.0 | 3.0 | ||
18 | 563 | 0.235 | 0.65 | 1.2 | 0.35 | 3.6 | 2.7 | ||
29 | 587 | 0.158 | 0.70 | 0.8 | 0.30 | 1.4 | 1.0 | ||
39 | 590 | 0.82 | 0.6 | 0.18 | 1.1 | 0.7 | |||
PMMA | |||||||||
20 | 535 | 0.335 |
λem, <r>, αi, τi, and φ are the wavelength of the emission maximum, the steady-state anisotropy, the preexponential factors, the fluorescence lifetimes, and the fluorescence quantum yield, respectively. <τ> = (τ12 + τ12)/(τ1 + τ2).
Estimated from the quantum yield.