Figure 1.
Structures of Δ4-pregnane-3,20-dione (progesterone) and the cardiotonic steroid ouabain. Compounds with an unsaturated five-membered lactone ring are cardenolides and those with an unsaturated six-membered lactone ring are bufadienolides. In the formulae, bonds or atoms or groups above the plane of the ring system are depicted as solid wedges; those below the plane are depicted as open, dashed wedges.