TABLE 1.
kf, kb | α, β | γ, δ | κ, λ | μ, ν | ɛ, ϕ | σ, τ |
---|---|---|---|---|---|---|
kf, kb (ms−1) | — | — | 0.1, 1.0 | — | — | 0.003, 0.0002 |
keq (ms−1) | 0.5 | 0.005 | — | 0.01 | 0.05 | — |
zf | 0.5 | 1.5 | — | 1.5 | 0.25 | — |
zb | 1.0 | 1.5 | — | 1.5 | 0.25 | — |
Veq | −55 | −80 | — | −10 | 60 | — |
Forward rate constant kf is calculated as keq exp((V − Veq) × zf × F × R−1 × T−1) and backward rate constant kb as keq exp(−(V − Veq) × zb × F × R−1 × T−1). R, T, and F have their normal thermodynamic meanings.