Table 6.
Structural features of the less common E−E′−X and E−E′⋯X (E,E′ = S,Se, X = halogen) linear three-body systems and of some selected E−E′−X (E = S,Se, E′ = Te, X = halogen) fragments.
| Compound reference code | E | E′ | X | d(E–E′) (Å) | d(E′–X)(Å) | ∠ E–E′–X(°)§ | References |
|---|---|---|---|---|---|---|---|
| BOYXAO10 | S | S | Cl | 2.040* | 2.915* | 169.6* | [390] |
| FAVDUB | S | S | Cl | 2.053* | 2.863* | 166.9* | [391] |
| KOJHOG | S | S | Cl | 2.047* | 2.933* | 170.4* | [399] |
| PIGWIL | S | S | Cl | 2.087 | 2.825 | 165.1 | [401] |
| 2.179 | 2.573 | 168.3 | |||||
| KOJHUM | S | S | Br | 2.056* | 3.028* | 171.5* | [399] |
| CIKHUZ10 | S | S | I | 2.057* | 3.168* | 171.2* | [445] |
| JAKWAT | S | S | I | 2.057* | 3.150* | 173.1* | [446] |
| KOJJEY | S | S | I | 2.066* | 3.175* | 172.6* | [399] |
| PEHHOZ | S | S | I | 2.051 | 3.180 | 172.8 | [447] |
| QADHOS | S | Se | I | 2.218* | 3.149* | 168.3* | [383] |
| MURXOM | S | Se | Br | 2.285* | 3.007* | 175.0* | [386] |
| MURYAZ | S | Se | Br | 2.258* | 3.094* | 174.3* | [386] |
| MURXIG | S | Se | Cl | 2.273* | 2.920* | 174.8* | [386] |
| MURXUS | S | Se | Cl | 2.252 | 2.976 | 172.8 | [386] |
| CEQKOY | S | Se | Cl | 2.215 | 3.276 | 178.5 | [260] |
| KAXWEL | S | Se | Cl | 2.293 | 3.237 | 168.8 | [387] |
| NEDBAZ | S | Se | Cl | 2.136 | 3.212 | 171.9 | [389] |
| TAVXET | Se | Se | Cl | 2.440 | 2.778 | 172.1 | [38] |
| TAVXIX | Se | Se | Br | 2.424 | 2.830 | 166.7 | [38] |
| PEBPUH | Se | Se | Br | 2.403 | 3.036 | 174.2 | [419] |
| WOHDUS | Se | Se | Br | 2.529* | 2.689* | 174,4* | [420] |
| EZOYIB | Se | Te | I | 2.906 | 2.889 | 177.7 | [439] |
| FOBCEE | Se | Te | I | 2.618 | 3.251 | 173.5 | [364] |
| ISEUTE | Se | Te | I | 2.679 | 3.095 | 177.3 | [440] |
| ROMXEW | Se | Te | I | 2.721 | 2.967 | 177.5 | [214] |
| BSEUTE | Se | Te | Br | 2.616 | 3.054 | 175.6 | [370] |
| DEVHAN | Se | Te | Br | 2.769 | 2.761 | 175.2 | [363] |
| FOBBIH | Se | Te | Br | 2.678 | 2.898 | 173.9 | [317] |
| FOBBIH01 | Se | Te | Br | 2.673* | 2.907* | 173.7* | [317] |
| FOBCAA | Se | Te | Br | 2.572* | 3.096* | 172.9* | [364] |
| FOBCAA01 | Se | Te | Br | 2.582 | 3.086 | 174.0 | [364] |
| FOBCAB | Se | Te | Br | 2.648 | 2.854 | 174.8 | [364] |
| KIKPID | Se | Te | Br | 2.496* | 3.244* | 168.6* | [411] |
| NAHWIC | Se | Te | Br | 2.704* | 2.810* | 175.0* | [412] |
| NAWOI | Se | Te | Br | 2.763 | 2.744 | 177.0 | [412] |
| FOWMAF | Se | Te | Br | 2.540 | 3.289 | 174.3 | [318] |
| DEVGUG | Se | Te | Cl | 2.783 | 2.600 | 174.7 | [363] |
| FOBBED | Se | Te | Cl | 2.678 | 2.752 | 172.8 | [317] |
| FOBBUT | Se | Te | Cl | 2.664 | 2.701 | 175.6 | [364] |
| GANHIM | Se | Te | Cl | 2.592 | 2.972 | 171.6 | [365] |
| BETDAG | Te | Te | I | 3.283 | 2.814 | 166.7 | [434] |
| HOJJEV | Te | Te | I | 3.163 | 2.831 | 176.1 | [435] |
| HOJJEV01 | Te | Te | I | 3.158 | 2.817 | 175.6 | [436] |
| HOSCAT | Te | Te | I | 2.669* | 3.369* | 169.0* | [437] |
| HOSCEX | Te | Te | I | 2.644* | 3.329* | 167.8* | [437] |
§The angle values are rounded off to the first decimal. *Mean values.