Table 2.
ΔH Parameter | Without DMSO | With 2.5% (v/v) DMSO2 |
ΔHc (integrated)3 | 946 ± 17 | 1145 ± 24 |
ΔHc (calc)4 | 941 ± 17 | 1198 ± 20 |
ΔHv (fit)5 | 953 ± 17 | 1151 ± 17 |
ΔHv ([Pt] dependent)6 | 858 ± 84 | — |
1 Units are kjoules/mole.
2 Reported ΔH values are the sum of equilibria 1 and 2.
3 Average and S.D. for 10 separate experiments.
4 Obtained from fitted curve; average and S.D. for 10 separate experiments.
5 Scan-rate independent curve fitted ΔHv obtained from y-intercept of plot in Fig. 3 ▶.
6 Derived from slope of line in Fig. 4 ▶.