Table 2.
Wavenumber (cm−1) | Structural assignmentb | % of total secondary structure |
---|---|---|
1683 | Turns | 2 |
1672 | Turns/loops/(0, π) β-sheet | 21 |
1657 | Loops/disordered/α-helixc | 17 |
1644 | Random-coil | 38 |
1628 | β-sheet MT, 01 | 22 |
a Errors in the wavenumber are estimated to be ± 2 cm−1.
b There are three more bands, which have not been indicated in the table. The first one centered at 1695 cm−1, whose assignment is uncertain (its contribution to the total area of the amide I band is less than the 1%). The other two bands, at 1609 and 1615 cm−1, are assigned to side chains; they account for 5% of the whole area of the amide I band. The percentages of secondary structure on the third column of the table do not take into account these three bands.
c The assignment of this band is uncertain (see text for details).