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. Author manuscript; available in PMC: 2009 Feb 25.
Published in final edited form as: Tetrahedron Lett. 2008 Feb 25;49(9):1542–1545. doi: 10.1016/j.tetlet.2007.12.105

Table 2.

Selective activation of various glycosyl donors over n-pentenyl acceptor 20 and SEt acceptor 22

graphic file with name nihms40112t2.jpg
entry D A time product yield, % α/β ratio
1 3a 20 10 min 21 86 1.1/1

2 4a 20 20 min 21 85 3.3/1
3 5a 20 10 min 21 83 1/1.2
4 9 20 16 h 21 65a 1.6/1
5 2a 22 15 min 23 84 1.6/1
6 3a 22 20 min 23 87 2.0/1
7 5a 22 15 min 23 89 2.4/1
8 8 22 15 min 23 84 2.2/1
9 9 22 24 h 23 83a 2.4/1
a

the yield is based on the recovered acceptor