Table 3.
Parameters from the analysis of the [urea] and [KCl] upshifts at 37 and 10 °C
| 37 °C | 10 °C | |
|---|---|---|
| k−2 (s−1) | 3.3 ± 0.7 | 7.2 (±0.7) × 10−1 |
| K3o a | 2.7 (±0.9) × 105 | 3.2 (±0.6) × 103 |
| dlnK3/d[urea] b | −3.3 ± 0.1 M−1 | −3.5 ± 0.1 M−1 |
| k−3o (s−1) a c | 1.1 (±0.7) × 10−2 | 3.3 (±1.0) × 10−2 |
| k3o (s−1) a d | 3.0 (±2.2) × 103 | 1.0 (±0.4) × 102 |
| dlnk−3/d[urea] c | 1.1 ± 0.2 M−1 | |
| dlnk3/d[urea] e | −2.2 ± 0.2 M−1 | −2.5 ± 0.2 M−1 |
Xo is the value of X in DB (containing 0.12 M KCl and no urea)
Determined from a fit of the linear regions of the data in Fig 3a (0–1.5 M urea at 10 °C and 0–2.5 M urea at 37 °C)
Calculated from values of K3 (= k3/k−3) and k−3 in this table
Calculated from: dlnk3/d[urea] = dlnK3/d[urea] + dlnk−3/d[urea]