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. 2007 Dec 19;104(52):20737–20742. doi: 10.1073/pnas.0706407105

Table 2.

Entropic characteristics of complex formation between CB[7] and guests 1, 2, and 3 determined from ITC experiments (TΔS°) and M2 calculations (TΔSconfig°), with TΔSsolv = TΔS° − TΔSconfig°

Complex TΔSexp. total° TΔSconfig° TΔSsolv
CB[7]·1 −36 ± 2 −75 39
CB[7]·2 −18 ± 2 −63 45
CB[7]·3 −2 ± 2* −78 76

All quantities are given in kJ mol−1.

*Average of data presented in Table 1.