TABLE 1.
Summary of x-ray criteria for phase coexistence
| Criterion | See Fig. | Gel-fluid?* | Ld-Lo?* | Requires oriented samples? | Complications |
|---|---|---|---|---|---|
| 1 (Double Ds) | 4 | Yes | Yes | No | Sufficient but not necessary |
| 2a (Double ds obvious in I(q) plot) | 1 A | Yes | No | No | 1. Fluid WAXS peak often obscured in unoriented samples |
| 2. A single gel phase can have 2 d spacings† | |||||
| 2b (Double ds inferred from shape of q0(φ) plot) | 3 | No | Yes | Yes | Requires
|
| 3 (Double Sx-ray) | 2 | No | Yes | Yes | Requires modeling |
The phrases “gel-fluid?” and “Ld-Lo?” ask if the criterion is applicable to that type of phase coexistence.
The Lβ′ phase has two wide angle d spacings due to its distorted hexagonal lattice. However, both Lβ′ peaks are narrower (40) than fluid-phase peaks.
