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. 2008 Jul;17(7):1129–1137. doi: 10.1110/ps.033910.107

Figure 1.

Figure 1.

(A) Schematic of Cl–π interactions. The interaction is defined by the θ angle of the Cl atom relative to the plane of the ring. (B) Two geometries found in Cl–π interactions: (i) face-on and (ii) edge-on geometries. The geometry is defined by the difference between two distances, which are between the Cl atom and the centroid or the nearest atom of the aromatic ring.