1 |
204.3, qC |
|
|
|
204.2 |
|
|
|
2 |
78.7, CH |
4.96 d (11.6) |
C-1, C-1C, C-3, C-4, C-1′ |
H-1C, H-3, H-4ax, H-4eq
|
77.9 |
4.93 d (11.6) |
C-1, C-1C, C-3, C-4, C-1′ |
H-1C, H-3, H-4ax, H-4eq
|
3 |
42.8, CH |
3.48 m |
C-2, C-4, C-1′ |
H-2, H-4ax, H-4eq, H-1′ |
42.8 |
3.41 m |
C-2, C-4, C-1′ |
H-2, H-4ax, H-4eq, H-1′ |
4ax
|
28.5, CH2
|
3.11 dd (15.9 and 3.6) |
C-2, C-3, C-1′ |
H-3, H-2 |
28.2 |
3.08 dd (15.9 and 3.6) |
C-2, C-3, C-1′ |
H-3, H-2 |
4eq
|
|
3.27 dd (15.9 and 13.0) |
|
H-3, H-2 |
|
3.26 dd (15.9 and 13.0) |
|
|
4a |
137.2, qC |
|
|
|
137.2 |
|
|
|
5 |
102.2, CH |
7.05 s |
C-6, C-8a, C-7, C-10 |
H-10, H-1A, H-5A |
102.1 |
7.04 s |
C-6, C-8a, C-7, C-10 |
H-10, H-1A, H-5A |
6 |
160.4, qC |
|
|
|
160.4 |
|
|
|
7 |
111.7, qC |
|
|
|
111.6 |
|
|
|
7-CH3
|
9.4, CH3
|
2.47 s |
C-6, C-7, C-8 |
|
9.4 |
2.47 s |
C-6, C-7, C-8 |
|
8 |
156.9, qC |
|
|
|
157.0 |
|
|
|
8a |
109.4, qC |
|
|
|
109.4 |
|
|
|
9 |
165.7, qC |
|
|
|
165.7 |
|
|
|
9a |
108.9, qC |
|
|
|
108.9 |
|
|
|
10 |
117.4, CH |
6.63 s |
C-5, C-8a, C-9a, C-10a |
H-5, H-1A, H-4ax, H-4eq
|
117.4 |
6.61 s |
C-5, C-8a, C-9a, C-10a |
H-5, H-1A, H-4ax, H-4eq
|
10a |
139.5, qC |
|
|
|
139.4 |
|
|
|
1′ |
83.1, CH |
5.49 d (1.2) |
C-2, C-3, C-4, 1′-OCH3, C-2′ |
H-2, H-3, 1′-OCH3
|
83.1 |
5.46 d (1.2) |
C-2, C-3, C-4, 1′-OCH3, C-2′ |
H-2, H-3, 1′-OCH3
|
1′-OCH3
|
59.1, CH3
|
3.69 s |
C-1′, C-2′, C-3 |
|
59.4 |
3.69 s |
C-1′, C-2′, C-3 |
|
2′ |
213.5, qC |
|
|
|
213.4 |
|
|
|
3′ |
81.4, CH |
4.70 d (2.8) |
C-2′, C-4′, C-5′ |
H-4′, H-5′ |
81.3 |
4.71 d (2.8) |
C-2′, C-4′, C-5′ |
H-4′, H-5′ |
4′ |
69.6, CH |
4.84 dq (6.2 and 2.8) |
C-2′, C-3′, C-5′ |
H-5′, H-3′ |
69.6 |
4.84 dq (6.2 and 2.8) |
C-2′, C-3′, C-5′ |
H-5′, H-3′ |
5′ |
19.7, CH3
|
1.60 d (6.2) |
C-3′, C-4′ |
H-4′, H-3′ |
21.1 |
1.58 d (6.2) |
C-3′, C-4′ |
H-4′, H-3′ |
1A |
97.9, CH |
5.68 dd (9.6 and 2.0) |
C-6 |
H-3A, H-5A, H-2Aax, H-2Aeq, H-5, H-10 |
97.9 |
5.67 dd (9.6 and 2.0) |
C-6 |
H-5, H-10, H-3A, H-5A, H-2Aax, H-2Aeq
|
2Aax
|
38.0, CH2
|
2.25 ddd (12, 12 and 9.6) |
C-1A, C-3A, C-4A |
H-1A, H-4A, H-2Aeq
|
37.7 |
2.24 ddd (12, 12 and 9.6) |
C-1A, C-3A |
H-1A, H-4A |
2Aeq
|
|
2.72 ddd (12, 5.0 and 2.0) |
|
H-1A, H-3A, H-2Aax
|
|
2.73 ddd (12, 5.0 and 2.0) |
|
H-1A |
3A |
80.1, CH |
4.29 ddd (12, 9.0 and 5.0) |
C-1B, C-4A |
H-1A, H-1B, H-5A, H-2Aax, H-2Aeq
|
80.1 |
4.29 ddd (12, 9.0 and 5.0) |
C-1B, C-4A |
H-1A, H-1B, H-5A, H-2Aeq
|
4A |
76.1, CH |
3.63 t (9.0 Hz) |
C-3A, C-5A, C-6A |
H-2Aax, H3-6A |
76.1 |
3.63 t (9.0) |
C-3A, C-5A, C-6A |
H-2Aax, H3-6A |
5A |
73.9, CH |
4.00 dq (9.0 and 6.0) |
C-1A, C-3A, C-4A, C-6A |
H-1A, H-3A, H3-6A |
73.9 |
4.00 dq (9.0 and 6.0) |
C-4A, C-6A |
H-1A, H-3A, H3-6A |
6A |
19.4, CH3
|
1.71 d (6.0) |
C-4A, C-5A |
H-4A, H-5A |
19.6 |
1.71 d (6.0) |
C-4A, C-5A |
H-4A, H-5A |
1B |
99.4, CH |
5.05 dd (9.6 and 2.0) |
C-3A |
H-2Bax, H-2Beq, H-3A, H-3B, H-5B |
99.3 |
5.05 dd (9.6 and 2.0) |
C-3A |
H-3A, H-3B, H-5B, H-2Bax, H-2Beq
|
2Bax
|
41.6, CH2
|
2.15 ddd (12, 12 and 9.6) |
C-1B, C-3B, C-4B |
H-1B, H-4B |
41.6 |
2.17 ddd (12, 12 and 9.6) |
C-1B, C-3B |
H-1B, H-4B |
2Beq
|
|
2.65 ddd (12, 5.0 and 2.0) |
|
H-1B |
|
2.65 ddd (12, 5.0 and 2.0) |
|
H-1B |
3B |
72.4, CH |
4.16 ddd (12, 9.0 and 5.0) |
C-4B |
H-2Beq, H-1B, H-5B |
72.4 |
4.15 ddd (12, 9.0 and 5.0) |
C-1B, C-4B |
H-1B, H-5B |
4B |
78.7, CH |
3.58 t (9.0) |
C-3B, C-5B, C-6B |
H-2Bax, H3-6B |
78.7 |
3.58 t (9.0) |
C-3B, C-5B, C-6B |
H-2Bax, H-3B, H-5B, H3-6B |
5B |
74.6, CH |
3.75 dq (9.0 and 6.0) |
C-1B, C-3B, C-4B, C-6B |
H-1B, H-3B, H3-6B |
74.0 |
3.75 dq (9.0 and 6.2) |
C-4B, C-6B |
H-1B, H-3B, H-4B, H3-6B |
6B |
19.1, CH3
|
1.64 d (6.0) |
C-4B, C-5B |
H-5B |
19.3 |
1.64 d (6.2) |
C-4B, C-5B |
H-4B, H-5B |
1C |
101.9, CH |
5.39 dd (9.6 and 2.0) |
C-2 |
H-2, H-3C, H-5C, H-2Ceq
|
101.9 |
5.37 dd (9.6 and 2.0) |
C-2 |
H-2, H-3C, H-5C, H-2Ceq, H-2Cax
|
2Cax
|
38.7, CH2
|
2.02 ddd (12, 12 and 9.6) |
C-1C, C-3C, C-4C |
H-4C |
37.7 |
1.93 ddd (12, 12 and 9.6) |
C-3C |
H-4C |
2Ceq
|
|
2.99 ddd (12, 5.0 and 2.0) |
|
H-1C |
|
2.98 ddd (12, 5.0 and 2.0) |
|
H-1C, H-1D, H-3C, H-2Cax
|
3C |
81.7, CH |
4.06 ddd (12, 9.0 and 5.0) |
C-1D, C-4C |
H-1C, H-1D, H-5C, H-2Ceq
|
77.9 |
4.08 ddd (12, 9.0 and 5.0) |
C-1D, C-4C |
H-1C, H-5C, H-4C, H-2Ceq
|
4C |
76.3, CH |
3.46 t (9.0) |
C-3C, C-5C, C-6C |
H-2Cax, H3-6C |
76.5 |
3.48 t (9.0) |
C-3C, C-6C |
H-2Cax, H-5C, H-6C |
5C |
73.5, CH |
3.68 dq (9.0 and 6.0) |
C-4C, C-6C |
H-3C, H-1C, H3-6C |
73.4 |
3.68 dq (9.0 and 6.0) |
C-4C, C-6C |
H-1C, H-3C, H-4C, H3-6C |
6C |
19.7, CH3
|
1.59 d (6.0) |
C-4C, C-5C |
H-5C, H-4C |
19.4 |
1.57 d (6.0) |
C-4C, C-5C |
H-4C, H-5C |
1D |
100.4, CH |
4.78 dd (9.6 and 2.0) |
C-3C |
H-3D, H-5D, H-2Deq, H-3C |
94.9 |
5.22 dd (4.0 and 2.3) |
C-3C |
H-3D, H-2Ceq, H-2Deq, H-2Dax
|
2Dax
|
33.3, CH2
|
2.42 ddd (12, 12 and 9.6) |
C-1D, C-3D, C-4D |
H-1D |
34.6 |
2.02 ddd (14.4, 4.0 and 3.0) |
C-1D, C-3D |
H-1D, H-3D, H-2Deq, |
2Deq
|
|
2.18 ddd (12, 5.0 and 2.0) |
|
|
|
2.35 ddd (14.4, 3.0 and 2.3) |
|
H-1D, H-3D, H-2Dax
|
3D |
77.2, CH |
4.22 ddd (12, 5.0 and 2.5) |
C-1E, C-4D |
H-1D, H-2Deq, H-5D, H-1E |
75.2 |
4.39 ddd (3.0 3.0 and 3.0) |
C-1D, C-4D, C-5D, C-1E |
H-1D, H-2Dax, H-2Deq, H-1E |
4D |
70.2, CH |
4.10 br d (2.5) |
C-3D, C-5D |
H3-6D |
72.8 |
3.67 ddd (9.0 and 3.0) |
C-5D, C-6D |
H-5D, H3-6D |
5D |
74.6, CH |
3.71 dq (6.0 and 2.5) |
C-4D, C-6D |
H-1D, H-3D, H3-6D |
67.4 |
4.69 dq (9.0 and 6.2) |
C-4D, C-6D |
H-1D, H-4D, H3-6D |
6D |
19.4, CH3
|
1.54 d (6.0) |
C-4D, C-5D |
H-5D |
18.9 |
1.54 d (6.2) |
C-4D, C-5D |
H-4D, H-5D |
1E |
97.8, CH |
5.62 dd (9.6 and 2.0) |
C-3D |
H-5E, H-2Eax, H-2Eeq, H-3D |
98.7 |
5.44 dd (9.6 and 2.0) |
C-3D |
H-2Eax, H-2Eeq, H-3D, H-5E |
2Eax
|
40.3, CH2
|
2.00 ddd (12, 9.6 and 3.0) |
C-1E, C-3E, C-4E |
H-1E, H-2Eax
|
45.5 |
1.86 dd (13.0, and 9.0) |
C-1E, C-3E |
H-1E, H-4E, |
2Eeq
|
|
2.45 ddd (12, 3.0 and 2.0) |
|
|
|
2.41 dd (13.0 and 2.0) |
|
H-1E |
3E |
69.1, CH |
4.45 ddd (3.0, 3.0, and 3.0) |
C-4E |
H-4E |
71.4 |
|
|
|
3E-CH3
|
|
|
|
|
28.2 |
1.44 s |
C-3E, C-4E, C-2E |
H-4E |
4E |
72.4, CH |
3.62 dd (9.2 and 3.0) |
C-3E, C-5E |
H-2Eax, H-3E, H3-6E |
77.8 |
3.31 d (9.2) |
3E-CH3, C-5E, C-6E |
H-2Eax, H3-3E, H-5E, H3-6E |
5E |
71.2, CH |
4.42 dq (9.2 and 6.0) |
C-1E, C-4E, C-6E |
H3-6E, H-1E |
72.2 |
4.22 dq (9.2 and 6.0) |
|
H-1E, H3-6E |
6E |
17.9, CH3
|
1.61 d (6.0) |
C-4E, C-5E |
H-5E |
19.1 |
1.60 d (6.0) |
C-4E, C-5E |
H-4E, H-5E |