1 |
204.2, qC |
|
|
|
204.4 |
|
|
|
2 |
77.9, CH |
4.96 d (11.6) |
C-1, C-1C, C-3, C-4, C-1′ |
H-1C, H-3, H-4ax, H-4eq
|
77.9 |
4.96 d (11.6) |
C-1, C-1C, C-3, C-4, C-1′ |
H-1C, H-3, H-4ax, H-4eq
|
3 |
42.6, CH |
3.48 m |
C-2, C-4, C-1′ |
H-2, H-4ax, H-4eq, H-1′ |
42.6 |
3.48 m |
C-2, C-4, C-1′ |
H-2, H-4ax, H-4eq, H-1′ |
4ax
|
28.2, CH2
|
3.10 dd (15.9 and 3.6) |
C-2, C-3, C-1′ |
H-3, H-2 |
28.1 |
3.12 dd (15.9 and 3.6) |
C-2, C-3, C-1′ |
H-3, H-2 |
4eq
|
|
3.27 dd (15.9 and 13.0) |
|
H-3, H-2 |
|
3.26 dd (15.9 and 13.0) |
|
H-3, H-2 |
4a |
137.2, qC |
|
|
|
137.2 |
|
|
|
5 |
102.2, CH |
7.04 s |
C-6, C-8a, C-7, C-10 |
H-10, H-1A, H-5A |
102.2 |
7.04 s |
C-6, C-7, C-8a, C-10 |
H-10, H-1A, H-5A |
6 |
160.5, qC |
|
|
|
160.6 |
|
|
|
7 |
111.2, qC |
|
|
|
111.7 |
|
|
|
7-CH3
|
8.9, CH3
|
2.47 s |
C-6, C-7, C-8 |
|
8.9 |
2.48 s |
C-6, C-7, C-8 |
|
8 |
157.0, qC |
|
|
|
157.0 |
|
|
|
8a |
109.3, qC |
|
|
|
109.4 |
|
|
|
9 |
166.0, qC |
|
|
|
165.9 |
|
|
|
9a |
108.2, qC |
|
|
|
108.9 |
|
|
|
10 |
117.4, CH |
6.62 s |
C-5, C-8a, C-9a, C-10a |
H-5, H-1A, H-4ax, H-4eq
|
117.4 |
6.62 s |
C-5, C-8a, C-9a, C-10a |
H-5, H-1A, H-4ax, H-4eq
|
10a |
139.4, qC |
|
|
|
139.5 |
|
|
|
1′ |
83.0, CH |
5.49 d (1.2) |
C-2, C-3, C-4, 1′-OCH3, C-2′ |
H-2, H-3, 1′-OCH3
|
83.0 |
5.49 d (1.2) |
C-2, C-3, C-4, 1′-OCH3, C-2′ |
H-2, H-3, 1′-OCH3
|
1′-OCH3
|
59.1, CH3
|
3.71 s |
C-1′, C-2′, C-3 |
|
59.1 |
3.69 s |
C-1′, C-2′, C-3 |
|
2′ |
213.2, qC |
|
|
|
213.5 |
|
|
|
3′ |
81.0, CH |
4.71 d (2.8) |
C-2′, C-4′, C-5′ |
H-4′, H-5′ |
81.1 |
4.70 d (2.8) |
C-2′, C-4′, C-5′ |
H-4′, H-5′ |
4′ |
69.3, CH |
4.84 dq (6.2 and 2.8) |
C-2′, C-3′, C-5′ |
H-5′, H-3′ |
69.4 |
4.84 dq (6.0 and 2.8) |
C-2′, C-3′, C-5′ |
H-5′, H-3′ |
5′ |
20.7, CH3
|
1.60 d (6.2 Hz) |
C-3′, C-4′ |
H-4′, H-3′ |
20.7 |
1.59 d (6.0) |
C-3′, C-4′ |
H-4′, H-3′ |
1A |
97.9, CH |
5.67 d (9.6 and 2.0) |
C-6 |
H-5, H-5A, H-3A, H-2Aeq, H-10 |
98.0 |
5.63 dd (9.6 and 2.0) |
C-6 |
H-5, H-3A, H-5A, H-2Aeq
|
2Aax
|
37.6, CH2
|
2.25 ddd (12, 12 and 9.6) |
C-1A, C-3A |
H-4A, H-2Aeq
|
36.7 |
2.00 ddd (12.0, 12.0 and 9.6) |
C-1A, C-3A, C-4A |
H-4A, H-2Aeq
|
2Aeq
|
|
2.72 ddd (12, 5.0 and 2.0) |
|
H-1A, H-3A, H-2Aax
|
|
2.73 ddd (12.0, 5.0 and 2.0) |
|
H-1A, H-2Aax
|
3A |
80.0, CH |
4.28 ddd (12, 9.0 and 5.0) |
C-1B, C-4A |
H-1A, H-1B, H-5A |
74.2 |
4.35 ddd (12, 9.2 and 5.0) |
C-2A, 4A |
H-1A, H-5A |
4A |
75.9, CH |
3.63 t (9.0) |
C-3A, C-5A, C-6A |
H-2Aax, H3-6A |
75.4 |
3.63 t (9.2) |
C-3A, C-5A, C-6A |
H-2Aax, H3-6A |
5A |
73.8, CH |
3.99 dq (9.0 and 6.0) |
C-4A, C-6A |
H-1A, H-3A, H3-6A |
73.8 |
4.01 dq (9.2 and 6.0 Hz) |
C-1A, C-3A, C-4A, C-6A |
H-1A, H-3A, H3-6A |
6A |
19.0, CH3
|
1.71 d (6.0) |
C-5A, C-4A |
H-4A, H-5A |
19.4 |
1.70 d (6.0) |
C-4A, C-5A |
H-4A, H-5A |
1B |
99.4, CH |
5.05 dd (9.6 and 2.0) |
C-3A |
H-3B, H-3A, H-2Bax, H-2Beq, H-5B |
|
|
|
|
2Bax
|
41.2, CH2
|
2.17 ddd (12, 12 and 9.6) |
C-1B, C-3B |
H-1B, H-4B |
|
|
|
|
2Beq
|
|
2.65 ddd (12, 5.0 and 2.0) |
|
H-1B |
|
|
|
|
3B |
72.1, CH |
4.14 ddd (12, 9.0 and 5.0) |
C-4B |
H-1B, H-5B |
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|
|
|
4B |
78.5, CH |
3.58 t (9.0) |
C-5B, C-6B |
H-2Bax
|
|
|
|
|
5B |
73.7, CH |
3.75 dq (9.0 and 6.0) |
C-4B, C-6B |
H-1B, H-3B, H3-6B |
|
|
|
|
6B |
18.9, CH3
|
1.64 d (6.0) |
C-4B, C-5B |
H-5B |
|
|
|
|
1C |
101.6, CH |
5.40 dd (9.6 and 2.0) |
C-2 |
H-2, H-3C, H-5C, H-2Ceq
|
101.7 |
5.40 dd (9.6 and 2.0) |
C-2 |
H-2, H-5C, H-3C, H-2Ceq
|
2Cax
|
38.5, CH2
|
2.02 ddd (12, 12 and 9.6) |
C-3C |
H-4C |
38.4 |
2.02 ddd (12, 12 and 9.6) |
C-1C, C-3C, C-4C |
H-4C |
2Ceq
|
|
H-1C2.99 ddd (12, 5.0 and 2.0) |
|
|
|
2.99 ddd (12, 5.0 and 2.0) |
|
|
3C |
81.1, CH |
4.03 ddd (12, 9.0 and 5.0) |
C-1D, C-4C |
H-1C, H-1D, H-5C, H-2Ceq
|
81.6 |
4.06 ddd (12, 9.0 and 5.0) |
C-1D, C-4C |
H-1C, H-5C, H-1D |
4C |
76.3, CH |
3.48 t (9.0) |
C-3C, C-5C |
H-2Cax, H3-6C |
76.2 |
3.47 t (9.0) |
C-3C, C-5C, C-6C |
H-2Cax, H3-6C |
5C |
73.6, CH |
3.69 dq (9.0 and 6.0) |
C-4C, C-6C |
H-3C, H-1C, H3-6C |
73.3 |
3.67 dq (9.0 and 6.0) |
C-1C, C-4C, C-6C |
H-1C, H-3C, H3-6C |
6C |
18.7, CH3
|
1.58 d (6.0) |
C-4C, C-5C |
H-4C, H-5C |
18.9 |
1.60 d (6.0) |
C-4C, C-5C |
H-5C |
1D |
98.9, CH |
5.46 dd (9.6 and 2.0) |
C-3C |
H-3C, H-5D |
100.3 |
4.79 dd (9.6 and 2.0) |
C-3C |
H-3C, H-3D, H-5D |
2Dax
|
45.2, CH2
|
1.86 dd (13.0 and 9.6) |
C-1D, C-3D |
H-2Deq
|
33.1 |
2.42 ddd (12, 12 and 9.6) |
C-1D, C-3D, C-4D |
|
2Deq
|
|
2.33 dd (13.0 and 2.0) |
|
H-2Dax
|
|
2.18 ddd (12, 5.0 and 2.0) |
|
|
3D |
71.2, CH |
|
|
|
77.0 |
4.21 ddd (12, 5.0 and 2.5) |
C-1E, C-4D |
H-1D, H-5D, H-1E |
3D-CH3
|
27.9, CH3
|
1.50 s |
C-2D, C-4D, C-3D |
H-4D |
|
|
|
|
4D |
77.4, CH |
3.35 d (9.2) |
C-3D, C-5D |
|
69.9 |
4.10 br d (2.5) |
C-3D, C-5D |
H-5D, H3-6D |
5D |
72.1, CH |
4.29 dq (9.2 and 6.2) |
C-4D, C-6D |
H-1D |
72.1 |
3.75 dq (6.2 and 2.5) |
C-1D, C-4D, C-6D |
H-1D, H-3D, H-4D |
6D |
19.0, CH3
|
1.61 d (6.2 Hz) |
C-4D, C-5D |
H-5D, 3D-CH3
|
17.5 |
1.54 d (6.2) |
C-4D, C-5D |
H-4D, H-5D |
1E |
|
|
|
|
98.4 |
5.55 dd (9.6 and 2.0) |
C-3D |
H-2Eax, H-2Eeq, H-5E, H-3D |
2Eax
|
|
|
|
|
45.5 |
1.89 dd (13.0 and 9.6) |
C-1E, C-3E, C-4E |
H-1E, H-4E |
2Eeq
|
|
|
|
|
|
2.32 dd (13.0 and 2.0) |
|
H-1E |
3E |
|
|
|
|
71.2 |
- |
- |
- |
3E-CH3
|
|
|
|
|
28.2 |
1.50 s |
C-2E, C-4E, C-3E |
H-4E |
4E |
|
|
|
|
77.7 |
3.38 d (9.2) |
C-3E, C-5E |
H3-3E, H3-6E, H-2Eax
|
5E |
|
|
|
|
71.9 |
4.29 dq (9.2 and 6.0) |
C-1E, C-4E, C-6E |
H-1E, H3-6E |
6E |
|
|
|
|
19.0 |
1.61 d (6.0) |
C-4E, C-5E |
H-4E, H-5E |