Table 2.

¹³C NMR Data of Compounds 1-3^a,b

carbon	1c	1d	2c	3c	carbon	1c	1d	2c	3c
1	39.9	39.9	40.2	40.1	Q-1	99.3	99.6	99.5	99.4
2	27.4	27.1	27.6	27.4	-2	76.4	75.8	76.6	76.5
3	90.3	89.0	91.2	91.6	-3	76.4	75.8	76.4	76.7
4	40.6	40.3	40.7	40.6	-4	77.9	77.5	78.1	78.0
5	57.1	56.4	57.2	57.3	-5	70.9	70.5	71.1	71.3
6	18.3	18.7	18.5	18.5	-6	18.3	19.1	18.4	18.4
7	34.3	33.7	34.5	34.5	Q′-1	99.3	99.6	99.5	97.6
8	40.8	40.8	41.0	41.0	-2	75.5	75.7	75.8	76.1
9	48.0	47.4	48.3	48.0	-3	78.3	78.5	78.5	76.3
10	37.9	37.3	38.1	38.1	-4	77.3	77.0	77	78.1
11	24.6	24.0	24.8	24.7	-5	72.6	73.3	73.3	73.3
12	124.0	124.0	124.3	124.3	-6	18.2	19.1	18.4	18.4
13	143.7	144.3	143.9	143.3	Q″-1				99.4
14	42.6	42.3	42.8	42.8	-2				75.8
15	35.9	36.2	36.1	36.1	-3				78.5
16	74.1	73.8	74.3	74.3	-4				77.5
17	52.3	52.0	52.5	52.5	-5				73.0
18	41.5	41.3	41.8	41.9	-6				18.4
19	48.0	48.0	48.3	48.0	G-1	104.6	105.3	105.5	105.5
20	36.3	35.6	36.6	36.5	-2	81.2	83.2	81.2	81.3
21	78.6	77.4	78.8	78.7	-3	78.2	78.5	78.7	78.6
22	36.1	36.7	36.4	36.3	-4	71.8	71.8	72.0	72.0
23	28.4	28.5	28.6	28.7	-5	77.5	77.0	78.1	78.1
24	16.9	16.1	17.2	17.1	-6	69.8	70.2	69.4	69.0
25	16.2	17.2	16.4	16.3	G′-1	105.2	106.3	104.7	105.3
26	17.6	17.5	17.9	17.8	-2	76.2	76.1	75.9	75.8
27	27.4	27.5	27.5	27.4	-3	77.9	77.5	77.5	77.3
28	175.4	175.0	175.6	175.6	-4	71.9	72.3	72.1	72.1
29	29.4	29.5	29.6	29.5	-5	78.3	78.5	78.4	78.3
30	19.4	19.5	19.6	19.5	-6	63.1	62.8	63.4	63.3
MT-1	169.1	168.1	169.3	169.2	F-1	104.0	103.7	104.1	104.7
-2	129.1	128.9	129.3	129.2	-2	82.4	82.6	81.2	72.4
-3	144.0	142.5	144.2	144.1	-3	75.4	75.4	75.7	75.6
-4	24.4	23.9	24.7	24.5	-4	72.9	72.9	72.5	72.5
-5	41.0	40.7	41.2	41.3	-5	71.7	71.6	71.4	72.1
-6	81.0	80.1	81.3	81.2	-6	16.7	17.7	16.9	16.9
-7	144.1	144.4	144.3	144.2	X-1	107.1	107.3
-8	115.9	115.4	116.2	116.1	-2	75.6	76.3
-9	12.6	13.0	12.8	12.8	-3	77.8	78.1
-10	23.6	23.9	23.8	23.8	-4	71.1	71.0
MT′-1	169.6	168.0	169.8	169.8	-5	67.3	67.6
-2	128.4	128.3	128.6	128.8	A-1			106.1
-3	144.1	143.7	144.2	144.2	-2			71.6
-4	24.5	23.9	24.6	24.6	-3			73.1
-5	41.0	40.7	41.2	41.3	-4			70.0
-6	80.9	79.8	81.1	81.1	-5			66.3
-7	144.7	144.4	144.9	144.8	G″-1	95.2	95.5	95.4	95.4
-8	115.9	115.2	116.1	116.1	-2	77.1	76.7	77.3	77.2
-9	12.6	13.0	12.8	12.8	-3	79.5	79.4	79.6	79.6
-10	23.6	24.0	23.8	23.8	-4	71.4	71.4	71.3	71.3
MT″-1				168.8	-5	79.5	79.4	79.8	79.6
-2				128.8	-6	62.2	62.1	62.4	62.3
-3				143.8	R-1	101.1	101.6	101.3	101.3
-4				24.3	-2	72.2	72.7	72.0	72.1
-5				41.2	-3	72.9	72.9	73.0	73.2
-6				81.0	-4	84.0	83.4	84.2	84.0
-7				144.5	-5	68.8	68.8	69.0	69.0
-8				116.5	-6	18.3	19.0	18.5	18.3
-9				12.8	X′-1	106.9	106.7	107.1	107.0
-10				24.2	-2	77.1	76.5	77	77.0
					-3	78.4	78.7	78.6	78.5
					-4	71.1	71.2	71.1	71.0
					-5	67.3	67.5	67.5	67.5

^aδ (ppm) 125 MHz.

^bThe signals of the sugar carbons were assigned by HSQC-TOCSY and ¹³C NMR.

^cIn CD₃OD.

^dIn C₅D₅N with three drops of CD₃OD.