Table 2.
carbon | 1c | 1d | 2c | 3c | carbon | 1c | 1d | 2c | 3c |
---|---|---|---|---|---|---|---|---|---|
1 | 39.9 | 39.9 | 40.2 | 40.1 | Q-1 | 99.3 | 99.6 | 99.5 | 99.4 |
2 | 27.4 | 27.1 | 27.6 | 27.4 | -2 | 76.4 | 75.8 | 76.6 | 76.5 |
3 | 90.3 | 89.0 | 91.2 | 91.6 | -3 | 76.4 | 75.8 | 76.4 | 76.7 |
4 | 40.6 | 40.3 | 40.7 | 40.6 | -4 | 77.9 | 77.5 | 78.1 | 78.0 |
5 | 57.1 | 56.4 | 57.2 | 57.3 | -5 | 70.9 | 70.5 | 71.1 | 71.3 |
6 | 18.3 | 18.7 | 18.5 | 18.5 | -6 | 18.3 | 19.1 | 18.4 | 18.4 |
7 | 34.3 | 33.7 | 34.5 | 34.5 | Q′-1 | 99.3 | 99.6 | 99.5 | 97.6 |
8 | 40.8 | 40.8 | 41.0 | 41.0 | -2 | 75.5 | 75.7 | 75.8 | 76.1 |
9 | 48.0 | 47.4 | 48.3 | 48.0 | -3 | 78.3 | 78.5 | 78.5 | 76.3 |
10 | 37.9 | 37.3 | 38.1 | 38.1 | -4 | 77.3 | 77.0 | 77 | 78.1 |
11 | 24.6 | 24.0 | 24.8 | 24.7 | -5 | 72.6 | 73.3 | 73.3 | 73.3 |
12 | 124.0 | 124.0 | 124.3 | 124.3 | -6 | 18.2 | 19.1 | 18.4 | 18.4 |
13 | 143.7 | 144.3 | 143.9 | 143.3 | Q″-1 | 99.4 | |||
14 | 42.6 | 42.3 | 42.8 | 42.8 | -2 | 75.8 | |||
15 | 35.9 | 36.2 | 36.1 | 36.1 | -3 | 78.5 | |||
16 | 74.1 | 73.8 | 74.3 | 74.3 | -4 | 77.5 | |||
17 | 52.3 | 52.0 | 52.5 | 52.5 | -5 | 73.0 | |||
18 | 41.5 | 41.3 | 41.8 | 41.9 | -6 | 18.4 | |||
19 | 48.0 | 48.0 | 48.3 | 48.0 | G-1 | 104.6 | 105.3 | 105.5 | 105.5 |
20 | 36.3 | 35.6 | 36.6 | 36.5 | -2 | 81.2 | 83.2 | 81.2 | 81.3 |
21 | 78.6 | 77.4 | 78.8 | 78.7 | -3 | 78.2 | 78.5 | 78.7 | 78.6 |
22 | 36.1 | 36.7 | 36.4 | 36.3 | -4 | 71.8 | 71.8 | 72.0 | 72.0 |
23 | 28.4 | 28.5 | 28.6 | 28.7 | -5 | 77.5 | 77.0 | 78.1 | 78.1 |
24 | 16.9 | 16.1 | 17.2 | 17.1 | -6 | 69.8 | 70.2 | 69.4 | 69.0 |
25 | 16.2 | 17.2 | 16.4 | 16.3 | G′-1 | 105.2 | 106.3 | 104.7 | 105.3 |
26 | 17.6 | 17.5 | 17.9 | 17.8 | -2 | 76.2 | 76.1 | 75.9 | 75.8 |
27 | 27.4 | 27.5 | 27.5 | 27.4 | -3 | 77.9 | 77.5 | 77.5 | 77.3 |
28 | 175.4 | 175.0 | 175.6 | 175.6 | -4 | 71.9 | 72.3 | 72.1 | 72.1 |
29 | 29.4 | 29.5 | 29.6 | 29.5 | -5 | 78.3 | 78.5 | 78.4 | 78.3 |
30 | 19.4 | 19.5 | 19.6 | 19.5 | -6 | 63.1 | 62.8 | 63.4 | 63.3 |
MT-1 | 169.1 | 168.1 | 169.3 | 169.2 | F-1 | 104.0 | 103.7 | 104.1 | 104.7 |
-2 | 129.1 | 128.9 | 129.3 | 129.2 | -2 | 82.4 | 82.6 | 81.2 | 72.4 |
-3 | 144.0 | 142.5 | 144.2 | 144.1 | -3 | 75.4 | 75.4 | 75.7 | 75.6 |
-4 | 24.4 | 23.9 | 24.7 | 24.5 | -4 | 72.9 | 72.9 | 72.5 | 72.5 |
-5 | 41.0 | 40.7 | 41.2 | 41.3 | -5 | 71.7 | 71.6 | 71.4 | 72.1 |
-6 | 81.0 | 80.1 | 81.3 | 81.2 | -6 | 16.7 | 17.7 | 16.9 | 16.9 |
-7 | 144.1 | 144.4 | 144.3 | 144.2 | X-1 | 107.1 | 107.3 | ||
-8 | 115.9 | 115.4 | 116.2 | 116.1 | -2 | 75.6 | 76.3 | ||
-9 | 12.6 | 13.0 | 12.8 | 12.8 | -3 | 77.8 | 78.1 | ||
-10 | 23.6 | 23.9 | 23.8 | 23.8 | -4 | 71.1 | 71.0 | ||
MT′-1 | 169.6 | 168.0 | 169.8 | 169.8 | -5 | 67.3 | 67.6 | ||
-2 | 128.4 | 128.3 | 128.6 | 128.8 | A-1 | 106.1 | |||
-3 | 144.1 | 143.7 | 144.2 | 144.2 | -2 | 71.6 | |||
-4 | 24.5 | 23.9 | 24.6 | 24.6 | -3 | 73.1 | |||
-5 | 41.0 | 40.7 | 41.2 | 41.3 | -4 | 70.0 | |||
-6 | 80.9 | 79.8 | 81.1 | 81.1 | -5 | 66.3 | |||
-7 | 144.7 | 144.4 | 144.9 | 144.8 | G″-1 | 95.2 | 95.5 | 95.4 | 95.4 |
-8 | 115.9 | 115.2 | 116.1 | 116.1 | -2 | 77.1 | 76.7 | 77.3 | 77.2 |
-9 | 12.6 | 13.0 | 12.8 | 12.8 | -3 | 79.5 | 79.4 | 79.6 | 79.6 |
-10 | 23.6 | 24.0 | 23.8 | 23.8 | -4 | 71.4 | 71.4 | 71.3 | 71.3 |
MT″-1 | 168.8 | -5 | 79.5 | 79.4 | 79.8 | 79.6 | |||
-2 | 128.8 | -6 | 62.2 | 62.1 | 62.4 | 62.3 | |||
-3 | 143.8 | R-1 | 101.1 | 101.6 | 101.3 | 101.3 | |||
-4 | 24.3 | -2 | 72.2 | 72.7 | 72.0 | 72.1 | |||
-5 | 41.2 | -3 | 72.9 | 72.9 | 73.0 | 73.2 | |||
-6 | 81.0 | -4 | 84.0 | 83.4 | 84.2 | 84.0 | |||
-7 | 144.5 | -5 | 68.8 | 68.8 | 69.0 | 69.0 | |||
-8 | 116.5 | -6 | 18.3 | 19.0 | 18.5 | 18.3 | |||
-9 | 12.8 | X′-1 | 106.9 | 106.7 | 107.1 | 107.0 | |||
-10 | 24.2 | -2 | 77.1 | 76.5 | 77 | 77.0 | |||
-3 | 78.4 | 78.7 | 78.6 | 78.5 | |||||
-4 | 71.1 | 71.2 | 71.1 | 71.0 | |||||
-5 | 67.3 | 67.5 | 67.5 | 67.5 |
δ (ppm) 125 MHz.
The signals of the sugar carbons were assigned by HSQC-TOCSY and 13C NMR.
In CD3OD.
In C5D5N with three drops of CD3OD.