TABLE 1.
Acyl chain composition and main transition temperature Tc of the investigated lipids
Lipid | Acyl chains* | Tc† | Hydrophobic thickness (nm) |
---|---|---|---|
DMPC | 14:0 /14:0 | 23°C | 2.30 (Lα),‡ 2.62 (Lα),¶ 2.9 (Lα)** |
POPC | 16:0 /18:1(C9-C10) | −4°C | 2.58 (Lα)§ |
PhC | 16:0 (34%), 18:1 (32%), 18:2 (18%) | <0°C | 2.71 (Lα)¶, 2.9 (Lα)** |
DSPC | 18:0 /18:0 | 54.5°C | 2.95 (Lα),†‖ 3.06 (Lα),** 3.60 (Lβ)‖ |
Sph | 18:0 (49%), 24:1 (20%) | 35°C | In the range of DSPC as judged from the acyl chain lengths†† |
DMPC, DSPC, POPC, acyl chains at positions 1/2; PhC, Sph, major acyl chains with % occurrence in brackets.
Tc, main transition temperature from the gel (Lβ) to the liquid-crystalline (Lα) phase according to Marsh (72) and Meyer et al. (73).
Lewis and Engelman (74).
Nezil and Bloom (77).
Nagle and Tristram-Nagle (75).
Rinia et al. (78).
Cornell and Separovic (76).
No data available.