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. Author manuscript; available in PMC: 2008 Dec 1.
Published in final edited form as: Chem Asian J. 2008 Feb 1;3(2):164–194. doi: 10.1002/asia.200

Scheme 20.

Scheme 20

Trost’s Synthesis of The Spiroketal Subunit of (−)-Calyculin A. Cp=η5-cyclopentadienyl, (DHQD)PHN=dihydroquinidine 9-O-(9′-phenanthryl) ether, DIBALH=diisobutylaluminum hydride, PDC=pyridinium dichromate, TFA=trifluoroacetic acid, TsOH=p-toluenesulfonic acid.