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. Author manuscript; available in PMC: 2008 Nov 21.

Published in final edited form as: J Am Chem Soc. 2007 Oct 30;129(46):14500–14510. doi: 10.1021/ja076121h

Speciation plot for reaction of the diiron(III) intermediate with phenol. The intermediate ( ) decays at 2 s⁻¹ to give rise to the early formation phase of diiron(III) product ( ). Diiron(II) clusters ( ) that do not traverse the intermediate oxidize more slowly, with a rate constant of ~0.01 s⁻¹ to product. Solid lines represent one- or two-exponential fits to the data.

Inline graphic — Speciation plot for reaction of the diiron(III) intermediate with phenol. The intermediate ( ) decays at 2 s⁻¹ to give rise to the early formation phase of diiron(III) product ( ). Diiron(II) clusters ( ) that do not traverse the intermediate oxidize more slowly, with a rate constant of ~0.01 s⁻¹ to product. Solid lines represent one- or two-exponential fits to the data.