Table 3.
The 13C-NMR spectral data of polyynes 1-5, isolated from A. sinensis (CDCl3, 100 MHz)
Position compounds 1,3-5 [2] | 1 | 2 | 3 | 4 | 5 |
---|---|---|---|---|---|
1 [18] | 117.3 | 117.3 | 9.3 | 117.6 | 67.1 |
2 [17] | 135.7 | 135.8 | 30.7 | 135.6 | 45.7 |
3 [16] | 63.4 | 63.4 | 64.1 | 63.3 | 184.6 |
4 [15] | 78.2 | 78.4 | 80.7 | 76.3 | 75.7 |
5 [14] | 70.3 | 70.2 | 68.6 | 72.2 | 77.4 |
6 [13] | 68.7 | 68.7 | 68.9 | 70.7 | 67.9 |
7 [12] | 79.8 | 79.7 | 79.2 | 78.7 | 87.6 |
8 [11] | 58.5 | 58.6 | 58.7 | 62.2 | 59.1 |
9 [10] | 127.6 | 127.8 | 127.8 | 59.5 | 127.1 |
10 [9] | 134.6 | 134.4 | 134.6 | 57.7 | 135.8 |
11 [8] | 31.8 | 29.7 | 27.7 | 28.1 | 28.1 |
12 [7] | 29.3 | 29.1 | 29.3 | 31.7 | 27.3 |
13 [6] | 29.2 | 29.1 | 29.1 | 29.3 | 29.4 |
14 [5] | 29.1 | 28.9 | 29.2 | 29.1 | 29.4 |
15 [4] | 27.7 | 28.6 | 22.7 | 26.6 | 32.1 |
16 [3] | 22.6 | 27.6 | 31.8 | 22.8 | 22.9 |
17 [2] | 14.1 | 25.8 | 14.1 | 14.1 | 14.3 |
[1] | 64.7 | ||||
[1′] | 171.6 | ||||
[2′] | 21.1 | ||||
1-OCH3 | 58.9 |