. Author manuscript; available in PMC: 2008 Aug 15.

Published in final edited form as: J Am Chem Soc. 2006 Dec 13;128(49):15819–15823. doi: 10.1021/ja065573b

Table 3.

Molecular ions (M⁺) for the chain elongation alcohols from incubations with (R)- and (S)-[2-²H]IPP.

Enzyme	Allylic Substrate	GPP		NPP		E,E-FPP		E,Z-FPP
Enzyme	Allylic Substrate	R	S	R	S	R	S	R	S
Avian	DMAPP	154	155	154	155	222	224	222	224
Avian	GPP	-	-	-	-	222	223	222	223
E. coli	DMAPP	154	155	154	155	222	224	222	224
E. coli	GPP	-	-	-	-	222	223	222	223
A. tridentata	DMAPP	154	155	154	155	222	224	222	224
A. tridentata	GPP	-	-	-	-	222	223	222	223
BglCV	DMAPP	154	155	154	155	-	-	-	-