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ν(C-O) versus ν(Fe-CO) plots of hemoprotein-CO complexes. Data points for wt DevS642 (○) and H149A (△) are compared with values for wt and distal mutants of myoglobin from (64) (◆), and from cytochrome P450 and NO synthase (←) (36, 68). Also shown are proximal histidine mutants of heme oxygenase (□) (29, 30).
